In Windows, you can change the computer's description by editing the registry. You can do that using reg.exe (the command line utility) in the following manner,
reg add HKLM\SYSTEM\ControlSet001\Services\lanmanserver\parameters /v srvcomment /t reg_sz /d "New description"
reg add HKLM\SYSTEM\ControlSet003\Services\lanmanserver\parameters /v srvcomment /t reg_sz /d "New description"
You can also change a remote computer description in this manner,
reg add \\computername\HKLM\SYSTEM\ControlSet001\Services\lanmanserver\parameters /v srvcomment /t reg_sz /d "New description"
Note that reg add and what follows is one line. It's tested under Win XP, edit registry with caution. For more info, see Windows help on reg.exe